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  2. 石高全

石高全

石高全,1963年9月出生,理学博士学位,清华大学教授、博士生导师,教育部长江特聘教授。 2006年12月受聘于南通大学客座教授。

2018年3月1日22时35分因病医治无效在北京不幸逝世,享年55岁。

人物介绍

石高全,1963年9月出生,清华大学教授、博士生导师。

人物经历

1981-1985,南京大学化学化工学院,理学学士

1985-1988,南京大学化学系,理学硕士

1988-1990,南京大学化学系,南京大学化学系博士生

1990-1992,日本国东京农工业大学工学部留学(做博士论文)

1992回国,南京大学化学系,理学博士

1992-1993,南京大学化学系讲师

1993-1995,南京大学化学系副教授

1995-2000,南京大学化学系教授

2000-至今,清华大学化学系教授

2018年3月1日22时35分因病医治无效在北京不幸逝世,享年55岁。

人物成就

石教授自1992年以来一直从事导电高分子材料/纳米结构以及单片石墨的研究,近年来在石墨烯的化学合成与功能化等方面从事了系列研究工作,特别是在石墨烯增强高分子复合材料,石墨烯修饰电极以及共轭分子修饰石墨烯等方面取得了进展。至今发表SCI论文240余篇。一些论文发表在Science, J. Am. Chem. Soc., Chem. Soc. Rev.,等国际一流刊物上。论文被他人引用7700余次。获得过清华大学“清华之友优秀教师”奖。2002年获得国家自然科学基金杰出青年基金资助。2004年获得中国化学会巴斯夫“青年知识创新奖”。2004年获得国家自然科学基金二等奖(第二获奖人)。2005年获得国务院政府特殊津贴。每年招收博士生1-2名,硕士生1-2名。每年接受2-3名博士后从事石墨烯的可控制备与应用研究。

本实验室长期以来一直从事导电高分子材料和纳米碳材料的研究。研制了一系列高强度导电高分子材料,特别是电化学合成了强度超过金属铝的聚噻吩膜和力学性能优异的聚苯膜材料。探索了制备各种导电高分子膜材料以及导电高分子/导电纤维复合材料的新方法。利用固体模板和无模板方法制备了高度取向的导电高分子微米/纳米管和导电高分子微容器。对微型容器进行线形组装,并研究了其在生物传感器方面的应用。研制了驱动力强、响应速度快、寿命长的基于导电高分子的驱动器件,并开发了其在抓取生物细胞、微米/纳米粒子方面的应用。研究了基于导电高分子的各种干性粘附材料用于显示各种材料与物件的干性缝合,平面显示屏以及各种电子元件的悬挂与固定。

2022年11月15日,科睿唯安信息服务(北京)有限公司发布了其2022年度“高被引科学家”名单,石高全入选。

研究方向

石墨烯的合成,功能化与应用研究

导电高分子微/纳米结构及其器件的研究

学术成果

发表研究论著:

2013

1. Huang, L., Li, C., Yuan, W.J. and Shi, G.Q., Strong composite films with layered structures prepared by casting silk fibroin-graphene oxide hydrogels.Nanoscale, 2013,5(9): 3780-3786.

2. Meng, Y.N., Zhao, Y., Hu, C.G., Cheng, H.H., Hu, Y., Zhang, Z.P., Shi, G.Q. and Qu, L.T., All-graphene core-sheath microfibers for all-solid-state, stretchable fibriform supercapacitors and wearable electronic textiles.Advanced materials, 2013,25(16): 2326-2331.

3. Sun, Y.Q., Shi, G.Q., Graphene/polymer composites for 能量 applications.Journal of Polymer Science Part B-Polymer Physics, 2013,51(4): 231-253.

4. Yuan, W.J., Liu, A.R., Huang, L., Li, C. and Shi, G.Q., High-performance NO sensors based on chemically modified graphene.Advanced Materials, 2013,25(5): 766-771.

5. Li, Y.R., Sheng, K.X., Yuan, W.J. and Shi, G.Q., A high-performance flexible fibre-shaped electrochemical capacitor based on electrochemically reduced graphene oxide.Chemical Communications, 2013,49(3): 291-293.

6. Chen, J., Li, C. and Shi, G.Q., Graphene materials for electrochemical capacitors.Journal of Physical Chemistry Letters, 2013,4(8): 1244-1253.

2012

1. Huang, C.C., Sheng, K.X., Qu, L.T. and Shi, G.Q., Dry adhesion of polythiophene nanotube arrays with drag-induced direction dependence.Journal of Applied Polymer Science, 2012,124(5): 4047-4053.

2. 越南盾, Z.L., Jiang, C.C., Cheng, H.H., Zhao, Y., Shi, G.Q., Jiang, L. and Qu, L.T., Facile fabrication of light, flexible and multifunctional graphene fibers.Advanced Materials, 2012,24(14): 1856-1861.

3. Cheng, H.H., Zhao, Y., Fan, Y.Q., Xie, X.J., Qu, L.T. and Shi, G.Q., Graphene-quantum-dot assembled nanotubes: a new Platform for efficient Raman enhancement.ACS Nano, 2012,6(3): 2237-2244.

4. Sheng, K.X., Sun, Y.Q., Li, C., Yuan, W.J. and Shi, G.Q., Ultrahigh-rate supercapacitors based on electrochemically reduced graphene oxide for ac line-filtering.Scientific Reports, 2012,2: 247.

5. Feng, X.L., An, Y.X., Yao, Z.Y., Li, C. and Shi, G.Q., A turn-on fluorescent sensor for pyrophosphate based on the disassembly of mediated perylene diimide aggregates.ACS Applied Materials \u0026 Interfaces, 2012,4(2): 614-618.

6. Li, Y., Zhao, Y., Cheng, H.H., Hu, Y., Shi, G.Q., Dai, L.M. and Qu, L.T., doped graphene quantum dots with rich functional groups.Journal of the American Chemical Society, 2012,134(1): 15-18.

7. Luo, P.H., Li, C. and Shi, G.Q., Synthesis of gold@ dots composite nanoparticles for surface enhanced Raman scattering.Physical Chemistry Chemical Physics, 2012,14(20): 7360-7366.

8. Zhang, L., Li, C., Liu, A.R. and Shi, G.Q., Electrosynthesis of graphene oxide/polypyrene composite films and their applications for sensing organic vapors.Journal of Materials 化学, 2012,22(17): 8438-8443.

9. Wang, X.L., Bai, H., Jia, Y.Y., Zhi, L.J., Qu, L.T., Xu, Y.X., Li, C. and Shi, G.Q., Synthesis of CaCO/graphene composite crystals for ultra-strong structural materials.RSC Advances, 2012,2(5): 2154-2160.

10. Liu, A.R., Yuan, W.J. and Shi, G.Q., Electrochemical actuator based on polypyrrole/sulfonated graphene/graphene tri-layer film.Thin Solid Films, 2012,520(19): 6307-6312.

11. Zhao, Y., Hu, C.G., Hu, Y., Cheng, H.H., Shi, G.Q. and Qu, L.T., A versatile, ultralight, doped graphene framework.Angewandte Chemie-International Edition, 2012,51(45): 11371-11375.

12. Chen, J., Sheng, K.X., Luo, P.H., Li, C. and Shi, G.Q., Graphene hydrogels deposited in nickel foams for high-rate electrochemical capacitors.Advanced Materials, 2012,24(33): 4569-4573.

13. Hu, C.G., Zhao,Y., Cheng, H.H., Shi, G.Q., Dai, L.M. and Qu, L.T., Temary Pd/PtFe networks supported by 3D graphene for efficient and durable electrooxidation of formic acid.Chemical Communications, 2012,48(97): 11865-11867.

14. Huang, C.C., Li, C. and Shi, G.Q., Graphene based catalysts.能量 \u0026 EnvironmentalScience, 2012,5(10): 8848-8868.

15. Sun, Y.Q., Li, C. and Shi, G.Q., Nanoporous doped modified graphene as electrocatalyst for reduction reaction.Journal of Materials 化学, 2012,22(25): 12810-12816.

16. Li, C., Shi, G.Q., Three-dimensional graphene architectures.Nanoscale, 2012,4(18): 5549-5563.

2011

1. Xu,Y.X. and Shi,G.Q.,Assembly of chemically modified graphene: methods and applications. Journal of Materials 化学,2011. 21⑽: 3311-3323.

2. Li,Y.,Hu,Y.,Zhao,Y.,Shi,G.Q.,Deng,L.E.,Hou .,Y .B. and Qu,L.T.,An electrochemical avenue to green-luminescent graphene quantum dots as potential electron-acceptors for photovoltaics. Advanced Materials,2011. 23⑹: 776.

3. Sheng,K.X.,Xu,Y.X.,Li,C. and Shi,G.Q.,High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide. New Materials,2011,26⑴: 9-15.

4. Bai,H.,Li,C. and Shi,G.Q.,Functional composite materials based on chemically converted graphene. Advanced Materials,2011,23⑼: 1089-1115.

5. Xie,X.J.,Bai,H.,Shi,G.Q. and Qu,L.T.,Load-tolerant,highly strain-responsive graphene sheets. Journal of Materials 化学,2011,21⑺: 2057-2059.

6. Sun,Y.Q.,Wu,Q. and Shi,G.Q.,Graphene based new 能量 materials. Energy \u0026 Environmental Science,2011,4⑷: 1113-1132.

7. Huang,C.C.,Bai,H.,Li,C. and Shi,G.Q.,A graphene oxide/hemoglobin composite hydrogel for enzymatic catalysis in organic solvents. Chemical Communications,2011,47⒄: 4962-4964.

8. Yao,Z.Y.,Bai,H.,Li,C. and Shi,G.Q.,Colorimetric and fluorescent dual probe based on a polythiophene derivative for the detection of cysteine and homocysteine. Chemical Communications,2011,47(26): 7431-7433.

9. An,Y.X.,Bai,H.,Li,C. and Shi,G.Q.,Disassembly-driven colorimetric and fluorescent sensor for anionic surfactants in 液态水 based on a conjugated polyelectrolyte/dye complex. Soft Matter,2011,7⒂: 6873-6877.

10. Zhao,Y.,Bai,H.,Hu,Y.,Li,Y.,Qu,L.T.,Zhang,S.W. and Shi G.Q.,Electrochemical deposition of polyaniline nanosheets mediated by sulfonated polyaniline functionalized graphenes. Journal of Materials 化学,2011,21(36): 13978-13983.

11. Bai,H.,Sheng,K.X.,Zhang,大前锋,Li,C. and Shi,G.Q.,Graphene oxide/conducting polymer composite hydrogels. Journal of Materials Chemistry,2011,21(46): 18653-18658.

12. Sun,Y.Q.,Wu,Q.,Xu,Y.X.,Bai,H.,Li,C. and Shi,G.Q.,Highly conductive and flexible mesoporous graphitic films prepared by graphitizing the composites of graphene oxide and nanodiamond. Journal of Materials 化学,2011,21⒇: 7154-7160.

13. Xu,Y.X.,Sheng,K.X.,Li,C. and Shi,G.Q.,Highly conductive chemically converted graphene prepared from mildly oxidized graphene oxide. Journal of Materials Chemistry 2011,21⒇: 7376-7380.

14. Wu,Q.,Sun,Y.Q.,Bai,H. and Shi,G.Q.,High-performance supercapacitor electrodes based on graphene hydrogels modified with 2-aminoanthraquinone moieties. Physical Chemistry Chemical Physics,2011,13(23): 11193-11198.

15. Sun,Y.Q.,Wu,Q. and Shi,G.Q.,Supercapacitors based on self-assembled graphene organogels. Physical Chemistry Chemical Physics,2011,13(38): 17249-17254.

16. Sheng,K.X.,Bai,H.,Sun,Y.Q.,Li,C. and Shi,G.Q.,Layer-by-layer assembly of graphene/polyaniline multilayer films and their application for electrochromic devices. Polymer,2011,52(24): 5567-5572.

17. Li,C. and Shi,G.Q.,Synthesis and electrochemical applications of the composites of conducting polymers and chemically converted grapheme. Electrochimica Acta,2011,56(28): 10737-10743.

18. Li,YG娱乐,Bai,H.,Li,C. and Shi,G.Q.,Colorimetric assays for acetylcholinesterase activity and inhibitor screening based on the disassembly-assembly of a 液态水soluble polythiophene 导数 ACS Applied Materials \u0026Interfaces,2011,3⑷: 1306-1310.

19. Wang,X.L.,Bai,H. and Shi,G.Q.,Size fractionation of graphene oxide sheets by pH-assisted selective sedimentation. Journal of the American Chemical Society,2011,133⒃: 6338-6342.

20. Bai,H.,Li,C.,Wang,X.L. and Shi,G.Q.,On the gelation of graphene oxide. Journal of Physical Chemistry C,2011,115⒀: 5545-5551.

21. Chen,J.,Zhao,L.,Bai,H. and Shi,G.Q.,Electrochemical detection of dioxygen and peroxide by hemin immobilized on chemically converted grapheme. Journal of Electroanalytical Chemistry,2011. 657(1-2): 34-38.

22. Zhang,L. and Shi,G.Q.,Preparation of highly conductive graphene hydrogels for fabricating supercapacitors with high rate capability. Journal of Physical 化学 C,2011,115(34): 17206-17212.

23. Luo,P. H. and Shi,G.Q.,Progress in nanostructures of graphitic nitrides. Polymer Bulletin,2011,4: 82-90.

2010

1. Xu,Y.X.,Wu,Q.,Sun,Y.Q.,Bai,H.,and Shi,G.Q.,Three-Dimensional Self-Assembly of Graphene Oxide and 脱氧核糖核酸 into Multifunctional Hydrogels. Acs Nano,2010. 4⑿: 7358-7362.

2. Liu,A.R.,Li,C.,Bai,H.,and Shi,G.Q.,Electrochemical Deposition of 聚吡咯/Sulfonated Graphene Composite Films. Journal of Physical Chemistry C,2010. 114(51): 22783-22789.

3. Yao,Z.Y.,Bai,H.,Li,C.,and Shi,G.Q.,Analyte-induced aggregation of conjugated polyelectrolytes: role of the charged moieties and its sensing application. Chemical Communications,2010. 46(28): 5094-5096.

4. Yao,Z.Y.,Li,Y.G.,Li,C.,and Shi,G.Q.,Disassembly of conjugated polyelectrolyte aggregates and their application for colorimetric detection of surfactants in 液态水 Chemical Communications,2010. 46(45): 8639-8641.

5. Wang,X.L.,Bai,H.,Yao,Z.Y.,Liu,A.R.,and Shi,G.Q.,Electrically conductive and mechanically strong biomimetic chitosan/reduced graphene oxide composite films. Journal of Materials 化学,2010. 20(41): 9032-9036.

6. Zhao,Y.,Hu,Y.,Li,Y.,Zhang,H.,Zhang,S.W.,Qu,L.T.,Shi,G.Q.,and Dai,L.M.,Super-long aligned TiO2/ nanotube arrays. Nanotechnology,2010. 21(50).

7. Xie,X.J.,Qu,L.T.,Zhou,C.,Li,Y.,Zhu,J.,Bai,H.,Shi,G.Q.,and Dai,L.M.,An Asymmetrically surfaceModified Graphene Film Electrochemical Actuator. Acs Nano,2010. 4⑽: 6050-6054.

8. Li,Y.,Zhou,C.,Xie,X.J.,Shi,G.Q.,and Qu,L.T.,Spontaneous,catalyst-free formation of doped graphitic nanocages. Carbon,2010. 48⒁: 4190-4196.

9. Bai,H.,Li,C.,Wang,X.L.,and Shi,G.Q.,A pH-sensitive graphene oxide composite hydrogel. Chemical Communications,2010. 46⒁:2376-2378.

10. Gao,Y.W.,Bai,H.,and Shi,G.Q.,Electrosynthesis of oligo(methoxyl pyrene) for turn-on fluorescence detection of volatile aromatic compounds. Journal of Materials 化学,2010. 20⒂:2993-2998.

11. Hong,W.J.,Bai,H.,Xu,Y.X.,Yao,Z.Y.,Gu,Z.Z.,and Shi,G.Q.,Preparation of Gold Nanoparticle/Graphene Composites with Controlled Weight Contents and Their Application in Biosensors.Journal of Physical Chemistry C,2010. 114⑷:1822-1826.

12. Xu,Y.X.,Sheng,K.X.,Li,C,Shi,G.Q. Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process ACS Nano 2010,4⑺: 4324-4330.

13. Sheng,K.X.,Shi,G.Q.,Synthesis of discus-like Poly(3,4-ethylenedioxythiophene) nanoparticles using a bicellar templateSynthetic Metals,2010,160(11-12): 1354-1358.

14. Sun,YQ; Li,C; Xu,YX,Bai,H,Yao ZY,Shi GQ,Chemically converted graphene as substrate for immobilizing and enhancing the activity of a polymeric catalyst Chemical Communications,2010,46(26) :4740-4742.

15. Wu,Q; Xu,YX; Yao,ZY,Liu AR,Shi GQ,Supercapacitors Based on Flexible Graphene/Polyaniline Nanofiber Composite Films.ACS Nano,2010,4⑷: 1963-1970.

2009

1. Liu,A.R.,Zhao,L.,Bai,H.,Zhao,H.X.,Xing,X.H.,and Shi,G.Q.,聚吡咯 Actuator with a Bioadhesive surface for Accumulating Bacteria from Physiological Media. Acs Applied Materials \u0026 Interfaces,2009. 1⑷:951-955.

2. Chen,Y.Q.,Bai,H.,Hong,W.J.,and Shi,G.Q.,Fluorescence detection of mercury ions in aqueous media with the complex of a cationic oligopyrene derivative and oligothymine. Analyst,2009. 134⑽:2081-2086.

3. Xu,Y.X.,Hong,W.J.,Bai,H.,Li,C.,and Shi,G.Q.,Strong and ductile poly(vinyl 乙醇)/graphene oxide composite films with a layered structure. Carbon,2009. 47⒂:3538-3543.

4. Bai,H.,Xu,Y.X.,Zhao,L.,Li,C.,and Shi,G.Q.,Non-covalent functionalization of graphene sheets by sulfonated polyaniline. Chemical Communications,2009⒀:1667-1669.

5. Yao,Z.Y.,Feng,X.L.,Hong,W.J.,Li,C.,and Shi,G.Q.,A simple approach for the discrimination of nucleotides based on a 液态水soluble polythiophene derivative. Chemical Communications,2009(31):4696-4698.

6. Yao,Z.Y.,Feng,X.L.,Li,C.,and Shi,G.Q.,Conjugated polyelectrolyte as a colorimetric and fluorescent probe for the detection of glutathione. Chemical Communications,2009(39):5886-5888.

7. Li,C.,Bai,H.,and Shi,G.Q.,Conducting polymer nanomaterials: electrosynthesis and applications. Chemical Society Reviews,2009. 38⑻:2397-2409.

8. Feng,X.L.,Yao,Z.Y.,Li,C.,and Shi,G.Q.,Self-assembly of insulated molecular wires of a 液态水soluble cationic PPV and anionic dendrons. Chinese Science Bulletin,2009. 54⒁:2451-2456.

9. Zhao,L.,Xu,Y.X.,Qiu,T.F.,Zhi,L.J.,and Shi,G.Q.,Polyaniline electrochromic devices with transparent graphene electrodes. Electrochimica Acta,2009. 55⑵:491-497.

10. Zhao,L.,Tong,L.,Li,C.,Gu,Z.Z.,and Shi,G.Q.,聚吡咯 actuators with inverse 蛋白石 structures. Journal of Materials 化学,2009. 19⑾:1653-1658.

11. Tong,L.,Li,C.,Chen,F.E.,Bai,H.,Zhao,L.,and Shi,G.Q.,Flexible 三明治 Photodetectors Based on Thick Polythiophene Films. Journal of Physical Chemistry C,2009. 113⒄:7411-7415.

12. Xu,Y.X.,Zhao,L.,Bai,H.,Hong,W.J.,Li,C.,and Shi,G.Q.,Chemically Converted Graphene Induced Molecular Flattening of 5,10,15,20-Tetrakis(1-methyl-4-pyridinio)porphyrin and Its Application for Optical Detection of Cadmium(Ⅱ) Ions. Journal of the American Chemical Society,2009. 131(37):13490-13497.

13. Chapman,G.M.,Bai,H.,Li,C.,and Shi,G.Q.,Micro-nanoscale binary structured silver films fabricated by electrochemical deposition. Materials Chemistry and Physics,2009. 114⑴:120-124.

14. Bai,H.,Zhao,L.,Lu,C.H.,Li,C.,and Shi,G.Q.,Composite nanofibers of conducting polymers and hydrophobic insulating polymers: Preparation and sensing applications. Polymer,2009. 50⒁:3292-3301.

15. Chen,Y.Q. and Shi,G.Q.,Fluorescence Detection and Discrimination of ss- and ds-脱氧核糖核酸 with a 液态水 Soluble Oligopyrene Derivative. Sensors,2009. 9⑹:4164-4177.

16. Chen,Y.Q.,Bai,H.,Chen,Q.,Li,C.,and Shi,G.Q.,A water-soluble cationic oligopyrene derivative: Spectroscopic studies and sensing applications. Sensors and Actuators B-Chemical,2009. 138⑵:563-571.

2008

1. Lu,G.W.,Hong,W.J.,Tong,L.,Bai,H.,Wei,Y.,and Shi,G.Q.,Drying Enhanced Adhesion of Polythiophene Nanotubule Arrays on Smooth Surfaces. Acs Nano,2008. 2⑾:2342-2348.

2. Bai,H.,Li,C.,and Shi,G.Q.,Pyrenyl excimers induced by the crystallization of POSS moieties: Spectroscopic studies and sensing applications. Chemphyschem,2008. 9⒀:1908-1913.

3. Hong,W.J.,Xu,Y.X.,Lu,G.W.,Li,C.,and Shi,G.Q.,Transparent graphene/PEDOT-PSS composite films as counter electrodes of dye-sensitized solar cells. Electrochemistry Communications,2008. 10⑽:1555-1558.

4. Bai,H.,Li,C.,and Shi,G.Q.,Electrochemical Fabrication of Superhydrophobic Surfaces on Metal and Semiconductor Substrates. Journal of Adhesion Science and Technology,2008. 22⒂:1819-1839.

5. Xu,Y.X.,Bai,H.,Lu,G.W.,Li,C.,and Shi,G.Q.,Flexible graphene films via the filtration of 液态水soluble noncovalent functionalized graphene sheets. Journal of the American Chemical Society,2008. 130⒅:5856-+.

6. Ma,T.,Li,C.,and Shi,G.,Optically Active Supramolecular Complex Formed by Ionic Self-Assembly of Cationic Perylenediimide Derivative and Adenosine Triphosphate. Langmuir,2008. 24⑴:43-48.

7. Ma,T.,Li,C.,and Shi,G.Q.,

8. Yao,Z.Y.,Li,C.,and Shi,G.Q.,Optically Active Supramolecular Complexes of 液态水Soluble Achiral Polythiophenes and Folic Acid: Spectroscopic Studies and Sensing Applications. Langmuir,2008. 24(22):12829-12835.

9. Zhao,L.,Ma,T.,Bai,H.,Lu,G.W.,Li,C.,and Shi,G.Q.,Layer-by-layer deposited multilayer films of oligo(pyrenebutyric acid) and a perylene diimide derivative: Structure and photovoltaic properties. Langmuir,2008. 24⑻:4380-4387.

10. Bai,H.,Li,C.,and Shi,G.Q.,Rapid nitroaromatic compounds sensing based on oligopyrene. Sensors and Actuators B-Chemical,2008. 130⑵:777-782.

11. Wang,S.B.,Li,C.,and Shi,G.Q.,Photoresponsive properties of multilayers of conductive polymer and CdSe nanoparticles. Solar 能量 Materials and Solar Cells,2008. 92⑸:543-549.

12. Li,M.,Yuan,J.Y.,and Shi,G.Q.,Electrochemical fabrication of nanoporous 聚吡咯 thin films. Thin Solid Films,2008. 516⑿:3836-3840.

参考资料

全球第五,全国高校领先!.今日头条-清华大学.2022-11-26